As a normal nix user you can install the Oxygen GTK theme:

$ nix-env -i oxygen-gtk

KDE will run any scripts you place in ~/.kde/env on startup so this is a good place to set the GTK_PATH so that applications can find the theme engine. If the path is wrong/unset you will see errors like this:

Gtk-WARNING **: Unable to locate theme engine in module_path

To set Oxygen-GTK as the gtk theme create the following file and make it executable: ~/.kde/env/set-gtk-theme.sh

#!/bin/sh

export GTK_PATH=$GTK_PATH:~/.nix-profile/lib/gtk-2.0
export GTK2_RC_FILES=$GTK2_RC_FILES:~/.nix-profile/share/themes/oxygen-gtk/gtk-2.0/gtkrc